Which nuclei can a low-field spectrometer see?
Pick your magnet's field strength, then tap any element to see its best NMR isotope, where it lands in the 1.8–60 MHz range of the open-source Arduino spectrometer and amplifier, and how practical it is to measure.
Hydrogen
Top 3 most-usedRating: GoodThe reference nucleus. Highest γ of any stable nucleus, 100% abundant, spin-½.
Helium
OtherRating: NoAbout 1 ppm natural abundance. Needs enriched ³He gas.
Lithium
GoodRating: GoodSmall quadrupole moment (Q), so lines stay sharp. LiCl(aq) is the easy test sample.
Beryllium
HardRating: HardSensitivity is fine, but beryllium is toxic.
Boron
GoodRating: GoodBoric acid or borax. Watch for a background signal from borosilicate glass.
Carbon
Top 3 most-usedRating: HardRated Hard for a home rig: 1.1% abundance and long T₁, so it needs a neat liquid and hours of averaging. Gold because it is one of the most-used NMR nuclei.
Nitrogen
OtherRating: NoLow γ and broad quadrupolar lines. ¹⁵N (spin-½) needs isotopic enrichment.
Oxygen
OtherRating: No0.04% natural abundance.
Fluorine
Top 3 most-usedRating: GoodThe best non-¹H option. 100% abundant spin-½ with high γ. Try TFA or C₆F₆.
Neon
OtherRating: NoA gas with 0.27% abundance.
Sodium
GoodRating: GoodNaCl(aq) gives a strong, sharp line.
Magnesium
OtherRating: NoLow γ and quadrupolar.
Aluminium
GoodRating: GoodAl(H₂O)₆³⁺ gives a sharp line.
Silicon
HardRating: HardT₁ of minutes. Background signal from glass and the probe.
Phosphorus
GoodRating: GoodH₃PO₄. 100% abundant spin-½, easy.
Sulfur
OtherRating: No0.76% abundance and broad lines.
Chlorine
HardRating: HardOnly the Cl⁻ ion gives usable lines, and it needs a high field.
Argon
OtherRating: No usable isotopeNo stable isotope with a nuclear spin.
Potassium
OtherRating: NoLow γ and low receptivity, so the signal is very weak.
Calcium
OtherRating: No0.14% abundance.
Scandium
GoodRating: GoodSc³⁺(aq) works well despite being quadrupolar.
Titanium
OtherRating: NoLow γ and broad lines.
Vanadium
GoodRating: GoodVanadate or VOCl₃.
Chromium
OtherRating: NoLow γ, and most Cr compounds are paramagnetic.
Manganese
OtherRating: OKKMnO₄ only. Mn(II) is paramagnetic and gives no signal.
Iron
OtherRating: NoVery low γ and abundance.
Cobalt
GoodRating: GoodK₃[Co(CN)₆]. Diamagnetic Co(III) only.
Nickel
OtherRating: NoLow abundance, and most compounds are paramagnetic.
Copper
OtherRating: OKCu(I) only, e.g. [Cu(MeCN)₄]⁺. Cu(II) is paramagnetic.
Zinc
OtherRating: NoLow γ and abundance.
Gallium
GoodRating: GoodGa(NO₃)₃(aq).
Germanium
OtherRating: NoVery low γ.
Arsenic
OtherRating: OKOnly symmetric sites such as AsF₆⁻. Toxic.
Selenium
HardRating: HardMe₂Se works but is weak and smells awful.
Bromine
OtherRating: OKThe Br⁻ ion (NaBr) is fine. Covalent Br gives lines too broad to see.
Krypton
OtherRating: NoA gas with low γ.
Rubidium
GoodRating: GoodRbCl(aq).
Strontium
OtherRating: NoLow γ.
Yttrium
OtherRating: NoLow γ and very long T₁.
Zirconium
OtherRating: NoLow γ and broad lines.
Niobium
OtherRating: OKStrong but broad. Only symmetric NbCl₆⁻ or NbF₆⁻.
Molybdenum
OtherRating: NoMolybdate has a sharp line, but γ is too low.
Technetium
OtherRating: No usable isotopeRadioactive, with no stable isotope.
Ruthenium
OtherRating: NoLow γ.
Rhodium
OtherRating: NoVery low γ.
Palladium
OtherRating: NoLow γ and broad lines.
Silver
OtherRating: NoVery low γ and very long T₁.
Cadmium
HardRating: HardConcentrated Cd(ClO₄)₂ or CdMe₂ with heavy averaging. Toxic.
Indium
OtherRating: OKStrong but broad. Symmetric In(III) only.
Tin
HardRating: HardNeat SnCl₄ or SnMe₄ is doable with averaging. The best heavy spin-½ option after Tl.
Antimony
OtherRating: OKOnly SbCl₆⁻ or SbF₆⁻. Everything else is very broad.
Tellurium
HardRating: HardMe₂Te or Te(OH)₆ with averaging.
Iodine
OtherRating: OKI⁻ or IO₄⁻ only. Covalent iodine can't be seen.
Xenon
HardRating: HardA gas, so it needs a pressurized cell or hyperpolarization.
Caesium
OtherRating: OKVery small Q gives very sharp lines. Low γ keeps the signal modest.
Barium
OtherRating: NoLow γ and receptivity.
Lanthanum
OtherRating: OKLa(NO₃)₃(aq). Quadrupolar, with moderately broad lines.
Cerium
OtherRating: No usable isotopeNo stable isotope with a nuclear spin.
Praseodymium
OtherRating: NoPr³⁺ is paramagnetic, which erases the element's own signal.
Neodymium
OtherRating: NoNd³⁺ is paramagnetic, which erases the element's own signal.
Promethium
OtherRating: No usable isotopeRadioactive, with no stable isotope.
Samarium
OtherRating: NoSm³⁺ is paramagnetic, which erases the element's own signal.
Europium
OtherRating: NoEu³⁺ is paramagnetic, which erases the element's own signal.
Gadolinium
OtherRating: NoGd³⁺ is strongly paramagnetic, which erases the element's own signal.
Terbium
OtherRating: NoTb³⁺ is paramagnetic, which erases the element's own signal.
Dysprosium
OtherRating: NoDy³⁺ is paramagnetic, which erases the element's own signal.
Holmium
OtherRating: NoHo³⁺ is paramagnetic, which erases the element's own signal.
Erbium
OtherRating: NoEr³⁺ is paramagnetic, which erases the element's own signal.
Thulium
OtherRating: NoTm³⁺ is paramagnetic, which erases the element's own signal.
Ytterbium
OtherRating: NoOnly in diamagnetic Yb(II) compounds, which are air-sensitive.
Lutetium
OtherRating: NoEnormous Q, so lines are too broad to see.
Hafnium
OtherRating: NoLow γ and huge Q.
Tantalum
OtherRating: NoEnormous Q. Only TaF₆⁻, and only at a high field.
Tungsten
OtherRating: NoVery low γ.
Rhenium
OtherRating: OKKReO₄ (perrhenate) only.
Osmium
OtherRating: NoVery low γ.
Iridium
OtherRating: NoVery low γ.
Platinum
HardRating: HardConcentrated Na₂PtCl₆ with averaging. Expensive.
Gold
OtherRating: NoVery low γ.
Mercury
HardRating: HardDoable with neat HgMe₂, but that is extremely toxic. Don't.
Thallium
GoodRating: GoodVery sensitive and sharp. Very toxic.
Lead
HardRating: HardPbMe₄ or concentrated Pb(NO₃)₂ with averaging. Toxic.
Bismuth
OtherRating: OKStrong on paper (100% abundant, decent γ), but its large Q gives very broad lines. Only symmetric species such as Bi(NO₃)₃ in concentrated HNO₃.
Polonium
OtherRating: No usable isotopeEvery isotope is intensely radioactive (²⁰⁹Po is spin-½ but not something to put in a probe).
Astatine
OtherRating: No usable isotopeRadioactive, with no stable isotope. Only trace amounts exist.
Radon
OtherRating: No usable isotopeRadioactive gas with no stable isotope.
Francium
OtherRating: No usable isotopeRadioactive, with no stable isotope. Half-life of minutes.
Radium
OtherRating: No usable isotopeRadioactive. ²²³Ra has spin 3/2 but no NMR use outside specialist labs.
Actinium
OtherRating: No usable isotopeRadioactive. ²²⁷Ac has spin 3/2 but is far too hazardous to handle.
Thorium
OtherRating: No usable isotopeNatural thorium is ²³²Th, which has spin 0. ²²⁹Th (spin 5/2) is a rare, radioactive isotope.
Protactinium
OtherRating: No usable isotopeRadioactive. ²³¹Pa has spin 3/2 but is scarce and highly toxic.
Uranium
OtherRating: NoNatural uranium is 99.3% ²³⁸U, which has spin 0. ²³⁵U (0.72%) has very low γ. Radioactive and regulated.
Neptunium
OtherRating: No usable isotopeRadioactive. ²³⁷Np (spin 5/2) has only been seen in specialist solid-state work.
Plutonium
OtherRating: NoFirst observed in 2012, in solid PuO₂ at a national lab. Fissile and far too hazardous for a home rig.
Americium
OtherRating: No usable isotopeRadioactive. ²⁴¹Am (spin 5/2) exists only in microgram amounts, e.g. in smoke detectors.
Curium
OtherRating: No usable isotopeRadioactive and made only in reactors or accelerators, in amounts far too small (and too hazardous) for NMR.
Berkelium
OtherRating: No usable isotopeRadioactive and made only in reactors or accelerators, in amounts far too small (and too hazardous) for NMR.
Californium
OtherRating: No usable isotopeRadioactive and made only in reactors or accelerators, in amounts far too small (and too hazardous) for NMR.
Einsteinium
OtherRating: No usable isotopeRadioactive and made only in reactors or accelerators, in amounts far too small (and too hazardous) for NMR.
Fermium
OtherRating: No usable isotopeRadioactive and made only in reactors or accelerators, in amounts far too small (and too hazardous) for NMR.
Mendelevium
OtherRating: No usable isotopeRadioactive and made only in reactors or accelerators, in amounts far too small (and too hazardous) for NMR.
Nobelium
OtherRating: No usable isotopeRadioactive and made only in reactors or accelerators, in amounts far too small (and too hazardous) for NMR.
Lawrencium
OtherRating: No usable isotopeRadioactive and made only in reactors or accelerators, in amounts far too small (and too hazardous) for NMR.
Rutherfordium
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Dubnium
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Seaborgium
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Bohrium
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Hassium
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Meitnerium
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Darmstadtium
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Roentgenium
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Copernicium
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Nihonium
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Flerovium
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Moscovium
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Livermorium
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Tennessine
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Oganesson
OtherRating: No usable isotopeSuperheavy element made a few atoms at a time, with half-lives of seconds or less. No NMR is possible.
Receptivity is relative to ¹H at natural abundance, at the same field. Figures are approximate and taken from standard IUPAC-style tables. Ratings assume diamagnetic samples. As a rule of thumb for a home rig at low field, a receptivity of about 0.01 or more is practical, 10⁻³ to 10⁻² needs long averaging, and below 10⁻³ is impractical. Larmor frequency f = (γ/2π) × B₀.